Thermal StabilityofAnisoylKaempferolGlycosidesinJackBean (Canavalia ensiformis (L.) DC)andTheirEffect on α‑Glucosidase Inhibition

Sutedja, Anita Maya, Yanase, Emiko, Batubara, Irmanida, Fardiaz, Dedi and Lioe, Hanifah Nuryani Lioe Thermal StabilityofAnisoylKaempferolGlycosidesinJackBean (Canavalia ensiformis (L.) DC)andTheirEffect on α‑Glucosidase Inhibition. Journal of Agricultural and Food Chemistry.

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Abstract

Kaempferol glycosidesarefunctionalcomponentsofjackbean.Thechemicalstabilityofkaempferolglycosidesunder simulated foodprocessingconditionswasevaluatedinthisstudybysubjectingthemethanolextractandeachcompoundtoheat treatment. Duringtheheattreatment,rearrangementoftheanisoylgroupontherhamnosemoietyofthekaempferolglycosidewas observed, followedbyhydrolysisuponlong-termheattreatment.Oneofthetworegioisomersproducedunderheatingconditions showed higher α-glucosidase inhibitoryactivitythanthedominantanisoylkaempferolglycoside.Thisrearrangementreactionwas also observedupontheheattreatmentofmethyl-3-O-anisoyl-rhamnose, withtherearrangementfromthe3-positiontothe2- position occurringpreferentially.Theapproachadoptedinthisstudycanbeusedtodesignappropriatefoodprocessingconditions, which, inturn,willincreasethefunctionalvalueoffoods.

Item Type: Article
Uncontrolled Keywords: food processing,thermalstability,kaempferolglycosides,jackbean
Subjects: Agriculture and Food Technology
Depositing User: Christine Limbara
Date Deposited: 18 Sep 2025 08:46
Last Modified: 18 Sep 2025 08:46
URI: https://repositori.ukwms.ac.id/id/eprint/44505

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